Organic Solid-State Reactions : Solid-State Gabriel Reactions
نویسندگان
چکیده
منابع مشابه
Understanding solid/solid organic reactions.
The concept of an organic reaction between two macroscopic solid particles is investigated. Thus, we study several reactions that have been recently reported to proceed "in the solid phase" and clearly show that, in most cases, grinding the two solid reactants together results in the formation of a liquid phase. This is true both for catalytic transformations (e.g., aldol condensations and olig...
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Mathematical methods have been developed to evaluate solid-state kinetics. They generally fall into two categories: model-fitting or model-free (isoconversional). Modelfitting methods determine the kinetic triplet (model, frequency factor and activation energy) whereas isoconversional (model-free) methods generate the activation energy as a function of reaction progress without modelistic assum...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1991
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.111.7_359